{"id":5857,"date":"2025-04-02T19:51:53","date_gmt":"2025-04-02T11:51:53","guid":{"rendered":"https:\/\/www.51mdea.com\/5857.html"},"modified":"2025-04-02T19:51:53","modified_gmt":"2025-04-02T11:51:53","slug":"%e9%ab%98%e7%b2%be%e5%b0%96%e8%a1%8c%e4%b8%9a%e4%b8%ad%e7%9a%84%e7%b2%be%e5%87%86%e9%85%8d%e6%96%b9%e8%ae%be%e8%ae%a1%ef%bc%9a%e4%b8%89%e8%8b%af%e5%9f%ba%e7%a3%b7%e7%9a%84%e6%8a%80%e6%9c%af%e4%bc%98","status":"publish","type":"post","link":"https:\/\/www.51mdea.com\/5857.html","title":{"rendered":"\u9ad8\u7cbe\u5c16\u884c\u4e1a\u4e2d\u7684\u7cbe\u51c6\u914d\u65b9\u8bbe\u8ba1\uff1a\u4e09\u82ef\u57fa\u78f7\u7684\u6280\u672f\u4f18\u52bf"},"content":{"rendered":"

\u4e09\u57fa\u78f7\uff1a\u9ad8\u7cbe\u5c16\u884c\u4e1a\u4e2d\u7684\u914d\u65b9\u5927\u5e08<\/h1>\n

\u5728\u73b0\u4ee3\u5316\u5b66\u5de5\u4e1a\u4e2d\uff0c\u6709\u4e00\u79cd\u795e\u5947\u7684\u5316\u5408\u7269\uff0c\u5b83\u5c31\u50cf\u4e00\u4f4d\u6280\u827a\u7cbe\u6e5b\u7684\u8c03\u9999\u5e08\uff0c\u5728\u5404\u79cd\u590d\u6742\u7684\u5316\u5b66\u53cd\u5e94\u4e2d\u6e38\u5203\u6709\u4f59\u3002\u8fd9\u5c31\u662f\u4e09\u57fa\u78f7\uff08Triphenylphosphine, TPP\uff09\uff0c\u4e00\u79cd\u770b\u4f3c\u666e\u901a\u5374\u8574\u542b\u65e0\u9650\u53ef\u80fd\u7684\u6709\u673a\u78f7\u5316\u5408\u7269\u3002\u4f5c\u4e3a\u5316\u5b66\u754c\u7684"\u591a\u9762\u624b"\uff0c\u4e09\u57fa\u78f7\u4e0d\u4ec5\u5728\u5b66\u672f\u7814\u7a76\u4e2d\u5907\u53d7\u9752\u7750\uff0c\u5728\u5de5\u4e1a\u5e94\u7528\u4e2d\u4e5f\u5c55\u73b0\u51fa\u975e\u51e1\u7684\u9b45\u529b\u3002<\/p>\n

\u60f3\u8c61\u4e00\u4e0b\uff0c\u5982\u679c\u628a\u5316\u5b66\u53cd\u5e94\u6bd4\u4f5c\u70f9\u996a\uff0c\u90a3\u4e48\u4e09\u57fa\u78f7\u5c31\u662f\u90a3\u4f4d\u7ecf\u9a8c\u4e30\u5bcc\u7684\u4e3b\u53a8\uff0c\u80fd\u591f\u7cbe\u51c6\u5730\u63a7\u5236\u6bcf\u4e00\u9053"\u83dc\u80b4"\u7684\u5473\u9053\u548c\u8d28\u5730\u3002\u4ece\u7cbe\u7ec6\u5316\u5de5\u5230\u533b\u836f\u5236\u9020\uff0c\u4ece\u6750\u6599\u79d1\u5b66\u5230\u50ac\u5316\u5242\u5f00\u53d1\uff0c\u4e09\u57fa\u78f7\u90fd\u626e\u6f14\u7740\u4e0d\u53ef\u6216\u7f3a\u7684\u89d2\u8272\u3002\u5b83\u5c31\u50cf\u4e00\u4f4d\u9ed8\u9ed8\u5949\u732e\u7684\u5e55\u540e\u82f1\u96c4\uff0c\u5728\u5404\u79cd\u590d\u6742\u5de5\u827a\u4e2d\u53d1\u6325\u7740\u5173\u952e\u4f5c\u7528\u3002<\/p>\n

\u672c\u6587\u5c06\u5e26\u60a8\u6df1\u5165\u4e86\u89e3\u8fd9\u4f4d\u5316\u5b66\u754c\u7684"\u914d\u65b9\u5927\u5e08"\u3002\u6211\u4eec\u5c06\u4ece\u4e09\u57fa\u78f7\u7684\u57fa\u672c\u6027\u8d28\u51fa\u53d1\uff0c\u9010\u6b65\u63a2\u8ba8\u5176\u5728\u4e0d\u540c\u9886\u57df\u7684\u6280\u672f\u4f18\u52bf\u3002\u901a\u8fc7\u8be6\u5b9e\u7684\u6570\u636e\u5206\u6790\u3001\u751f\u52a8\u7684\u6848\u4f8b\u8bb2\u89e3\u4ee5\u53ca\u6743\u5a01\u6587\u732e\u7684\u652f\u6301\uff0c\u8ba9\u60a8\u5168\u9762\u8ba4\u8bc6\u8fd9\u4e00\u795e\u5947\u5316\u5408\u7269\u7684\u72ec\u7279\u9b45\u529b\u3002\u65e0\u8bba\u60a8\u662f\u5316\u5b66\u9886\u57df\u7684\u4e13\u4e1a\u4eba\u58eb\uff0c\u8fd8\u662f\u5bf9\u79d1\u5b66\u5145\u6ee1\u597d\u5947\u7684\u7231\u597d\u8005\uff0c\u8fd9\u7bc7\u6587\u7ae0\u90fd\u5c06\u4e3a\u60a8\u6253\u5f00\u4e00\u6247\u901a\u5411\u4e09\u57fa\u78f7\u4e16\u754c\u7684\u5927\u95e8\u3002<\/p>\n

\u57fa\u672c\u6027\u8d28\u4e0e\u7ed3\u6784\u7279\u5f81\uff1a\u4e09\u57fa\u78f7\u7684"\u8eab\u4efd\u8bc1"<\/h2>\n

\u4e09\u57fa\u78f7\uff0c\u8fd9\u4e2a\u542c\u8d77\u6765\u7565\u663e\u62d7\u53e3\u7684\u540d\u5b57\uff0c\u5176\u5b9e\u6709\u7740\u76f8\u5f53\u7b80\u6d01\u660e\u4e86\u7684\u5316\u5b66\u7ed3\u6784\u3002\u5b83\u7684\u5206\u5b50\u5f0f\u4e3aC18H15P\uff0c\u7531\u4e09\u4e2a\u73af\u901a\u8fc7\u5171\u4ef7\u952e\u8fde\u63a5\u5728\u4e00\u4e2a\u78f7\u539f\u5b50\u4e0a\u6784\u6210\u3002\u8fd9\u79cd\u72ec\u7279\u7684\u7ed3\u6784\u8d4b\u4e88\u4e86\u4e09\u57fa\u78f7\u8bb8\u591a\u5f15\u4eba\u6ce8\u76ee\u7684\u7269\u7406\u5316\u5b66\u7279\u6027\uff0c\u4f7f\u5176\u5728\u4f17\u591a\u5316\u5b66\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u8272\u3002<\/p>\n

\u5206\u5b50\u7ed3\u6784\u4e0e\u7a7a\u95f4\u6784\u578b<\/h3>\n

\u4e09\u57fa\u78f7\u7684\u7a7a\u95f4\u6784\u578b\u5448\u73b0\u51fa\u4e00\u4e2a\u5b8c\u7f8e\u7684\u4e09\u89d2\u53cc\u9525\u5f62\u3002\u4e2d\u5fc3\u78f7\u539f\u5b50\u91c7\u53d6sp3d\u6742\u5316\uff0c\u4e0e\u4e09\u4e2a\u57fa\u5f62\u6210\u7b49\u8fb9\u4e09\u89d2\u5f62\u6392\u5217\u3002\u6bcf\u4e2a\u57fa\u901a\u8fc7\u5176\u4e0a\u7684\u78b3\u539f\u5b50\u4e0e\u78f7\u539f\u5b50\u76f8\u8fde\uff0c\u5f62\u6210\u4e86\u4e00\u4e2a\u5e73\u9762\u89d2\u5ea6\u7ea6\u4e3a92.4\u00b0\u7684\u7a33\u5b9a\u7ed3\u6784\u3002\u8fd9\u79cd\u7279\u6b8a\u7684\u51e0\u4f55\u5f62\u72b6\u4f7f\u4e09\u57fa\u78f7\u5728\u914d\u4f4d\u5316\u5b66\u4e2d\u5177\u6709\u4f18\u5f02\u7684\u7535\u5b50\u7279\u6027\u548c\u7acb\u4f53\u9009\u62e9\u6027\u3002<\/p>\n\n\n\n\n\n\n\n\n
\u7269\u7406\u53c2\u6570<\/th>\n\u6570\u503c<\/th>\n<\/tr>\n<\/thead>\n
\u5206\u5b50\u91cf<\/td>\n262.29 g\/mol<\/td>\n<\/tr>\n
\u5bc6\u5ea6<\/td>\n1.17 g\/cm\u00b3<\/td>\n<\/tr>\n
\u7194\u70b9<\/td>\n80-82 \u00b0C<\/td>\n<\/tr>\n
\u6cb8\u70b9<\/td>\n360 \u00b0C (\u5206\u89e3)<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u5316\u5b66\u7a33\u5b9a\u6027\u4e0e\u53cd\u5e94\u6d3b\u6027<\/h3>\n

\u4e09\u57fa\u78f7\u4ee5\u5176\u51fa\u8272\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u8457\u79f0\u3002\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\uff0c\u5b83\u662f\u4e00\u79cd\u767d\u8272\u6676\u4f53\u7c89\u672b\uff0c\u4e0d\u6613\u53d1\u751f\u81ea\u53d1\u5206\u89e3\u6216\u6c27\u5316\u53cd\u5e94\u3002\u7136\u800c\uff0c\u5f53\u9047\u5230\u9002\u5f53\u7684\u53cd\u5e94\u6761\u4ef6\u65f6\uff0c\u4e09\u57fa\u78f7\u53c8\u80fd\u5c55\u73b0\u51fa\u60ca\u4eba\u7684\u53cd\u5e94\u6d3b\u6027\u3002\u4f8b\u5982\uff0c\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\uff0c\u5b83\u53ef\u4ee5\u4e0e\u5364\u4ee3\u70c3\u53d1\u751f\u4eb2\u6838\u53d6\u4ee3\u53cd\u5e94\uff0c\u751f\u6210\u76f8\u5e94\u7684\u78f7\u5316\u7269\uff1b\u5728\u9178\u6027\u73af\u5883\u4e2d\uff0c\u5219\u80fd\u5f62\u6210\u7a33\u5b9a\u7684\u78f7\u9178\u916f\u3002<\/p>\n

\u7279\u522b\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u4e09\u57fa\u78f7\u5177\u6709\u5f88\u5f3a\u7684\u4eb2\u6838\u6027\u3002\u5176\u78f7\u539f\u5b50\u5e26\u6709\u90e8\u5206\u8d1f\u7535\u8377\uff0c\u80fd\u591f\u8f7b\u6613\u653b\u51fb\u7f3a\u7535\u5b50\u4e2d\u5fc3\uff0c\u53c2\u4e0e\u591a\u79cd\u91cd\u8981\u7684\u6709\u673a\u5408\u6210\u53cd\u5e94\u3002\u540c\u65f6\uff0c\u5b83\u8fd8\u5177\u5907\u826f\u597d\u7684\u914d\u4f4d\u80fd\u529b\uff0c\u53ef\u4ee5\u4e0e\u91d1\u5c5e\u79bb\u5b50\u5f62\u6210\u7a33\u5b9a\u7684\u914d\u5408\u7269\uff0c\u8fd9\u4e3a\u5176\u5728\u50ac\u5316\u9886\u57df\u7684\u5e7f\u6cdb\u5e94\u7528\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/p>\n

\u7279\u6b8a\u6027\u8d28\u4e0e\u529f\u80fd\u7279\u6027<\/h3>\n

\u4e09\u57fa\u78f7\u7684\u53e6\u4e00\u4e2a\u7a81\u51fa\u7279\u70b9\u662f\u5176\u4e24\u4eb2\u6027\u3002\u4e00\u65b9\u9762\uff0c\u7531\u4e8e\u57fa\u7684\u5b58\u5728\uff0c\u5b83\u5177\u6709\u4e00\u5b9a\u7684\u758f\u6c34\u6027\uff1b\u53e6\u4e00\u65b9\u9762\uff0c\u78f7\u539f\u5b50\u4e0a\u7684\u5b64\u5bf9\u7535\u5b50\u53c8\u8d4b\u4e88\u5176\u4eb2\u6c34\u7279\u6027\u3002\u8fd9\u79cd\u53cc\u91cd\u5c5e\u6027\u4f7f\u5f97\u4e09\u57fa\u78f7\u80fd\u591f\u5728\u6cb9\u6c34\u754c\u9762\u53d1\u6325\u72ec\u7279\u7684\u4f5c\u7528\uff0c\u6210\u4e3a\u8bb8\u591a\u4e73\u5316\u4f53\u7cfb\u548c\u8868\u9762\u6d3b\u6027\u5242\u7684\u7406\u60f3\u9009\u62e9\u3002<\/p>\n

\u6b64\u5916\uff0c\u4e09\u57fa\u78f7\u8fd8\u5177\u6709\u663e\u8457\u7684\u8367\u5149\u7279\u6027\u3002\u5728\u7d2b\u5916\u5149\u7167\u5c04\u4e0b\uff0c\u5b83\u4f1a\u53d1\u51fa\u660e\u4eae\u7684\u84dd\u7eff\u8272\u8367\u5149\uff0c\u8fd9\u4e00\u7279\u6027\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u751f\u7269\u6807\u8bb0\u548c\u5149\u5b66\u4f20\u611f\u9886\u57df\u3002\u6b63\u5982\u4e00\u4f4d\u8eab\u6000\u7edd\u6280\u7684\u6b66\u6797\u9ad8\u624b\uff0c\u4e09\u57fa\u78f7\u5728\u4e0d\u540c\u7684\u5e94\u7528\u573a\u666f\u4e2d\u603b\u80fd\u5c55\u73b0\u51fa\u4ee4\u4eba\u60ca\u53f9\u7684\u7279\u6b8a\u672c\u9886\u3002<\/p>\n

\u6280\u672f\u4f18\u52bf\u5256\u6790\uff1a\u4e09\u57fa\u78f7\u7684\u72ec\u95e8\u7edd\u6280<\/h2>\n

\u5982\u679c\u8bf4\u4e09\u57fa\u78f7\u662f\u4e00\u628a\u4e07\u80fd\u94a5\u5319\uff0c\u90a3\u4e48\u5b83\u7684\u6280\u672f\u4f18\u52bf\u5c31\u5982\u540c\u8fd9\u628a\u94a5\u5319\u4e0a\u7cbe\u5999\u7684\u9f7f\u7eb9\u8bbe\u8ba1\uff0c\u8ba9\u5176\u80fd\u5728\u5404\u79cd\u590d\u6742\u573a\u5408\u6e38\u5203\u6709\u4f59\u3002\u8ba9\u6211\u4eec\u9010\u4e00\u63ed\u5f00\u8fd9\u4e9b"\u72ec\u95e8\u7edd\u6280"\u7684\u795e\u79d8\u9762\u7eb1\uff0c\u770b\u770b\u5b83\u4eec\u662f\u5982\u4f55\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u53d1\u6325\u4f5c\u7528\u7684\u3002<\/p>\n

\u9ad8\u6548\u50ac\u5316\u6027\u80fd<\/h3>\n

\u5728\u50ac\u5316\u9886\u57df\uff0c\u4e09\u57fa\u78f7\u582a\u79f0"\u91d1\u724c\u8c03\u89e3\u5458"\u3002\u5b83\u80fd\u591f\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u5f62\u6210\u7a33\u5b9a\u7684\u914d\u5408\u7269\uff0c\u8c03\u63a7\u53cd\u5e94\u8def\u5f84\u5e76\u964d\u4f4e\u6d3b\u5316\u80fd\u3002\u4ee5\u7ecf\u5178\u7684Stille\u5076\u8054\u53cd\u5e94\u4e3a\u4f8b\uff0c\u4e09\u57fa\u78f7\u4e0e\u94af\u50ac\u5316\u5242\u534f\u540c\u4f5c\u7528\uff0c\u53ef\u6709\u6548\u4fc3\u8fdb\u6709\u673a\u9521\u8bd5\u5242\u4e0e\u5364\u4ee3\u82b3\u70c3\u4e4b\u95f4\u7684\u4ea4\u53c9\u5076\u8054\u3002\u8fd9\u79cd\u53cd\u5e94\u5728\u836f\u7269\u5408\u6210\u548c\u65b0\u6750\u6599\u5236\u5907\u4e2d\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n

\u66f4\u4ee4\u4eba\u79f0\u9053\u7684\u662f\uff0c\u4e09\u57fa\u78f7\u8fd8\u80fd\u5b9e\u73b0"\u667a\u80fd\u8c03\u63a7"\u3002\u901a\u8fc7\u6539\u53d8\u53cd\u5e94\u6761\u4ef6\u6216\u5f15\u5165\u8f85\u52a9\u914d\u4f53\uff0c\u5b83\u53ef\u4ee5\u7075\u6d3b\u8c03\u6574\u50ac\u5316\u6548\u7387\u548c\u9009\u62e9\u6027\u3002\u8fd9\u5c31\u597d\u6bd4\u4e00\u4f4d\u7ecf\u9a8c\u4e30\u5bcc\u7684\u53a8\u5e08\uff0c\u6839\u636e\u98df\u6750\u7684\u4e0d\u540c\u7279\u6027\uff0c\u968f\u65f6\u8c03\u6574\u706b\u5019\u548c\u8c03\u5473\uff0c\u786e\u4fdd\u6bcf\u4e00\u9053\u83dc\u54c1\u90fd\u80fd\u8fbe\u5230\u4f73\u6548\u679c\u3002<\/p>\n\n\n\n\n\n\n\n
\u53cd\u5e94\u7c7b\u578b<\/th>\n\u50ac\u5316\u6548\u7387<\/th>\n\u9009\u62e9\u6027 (%)<\/th>\n<\/tr>\n<\/thead>\n
Stille\u5076\u8054<\/td>\n>95%<\/td>\n98-99<\/td>\n<\/tr>\n
Suzuki\u5076\u8054<\/td>\n>90%<\/td>\n97-98<\/td>\n<\/tr>\n
Heck\u53cd\u5e94<\/td>\n>92%<\/td>\n96-97<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u4f18\u826f\u7684\u914d\u4f4d\u80fd\u529b<\/h3>\n

\u4e09\u57fa\u78f7\u7684\u53e6\u4e00\u5927\u4f18\u52bf\u5728\u4e8e\u5176\u5353\u8d8a\u7684\u914d\u4f4d\u80fd\u529b\u3002\u5b83\u53ef\u4ee5\u901a\u8fc7\u78f7\u539f\u5b50\u4e0a\u7684\u5b64\u5bf9\u7535\u5b50\u4e0e\u591a\u79cd\u91d1\u5c5e\u79bb\u5b50\u5f62\u6210\u7a33\u5b9a\u7684\u914d\u5408\u7269\uff0c\u8fd9\u4f7f\u5176\u5728\u914d\u4f4d\u5316\u5b66\u4e2d\u626e\u6f14\u7740\u91cd\u8981\u89d2\u8272\u3002\u4f8b\u5982\uff0c\u5728\u948c\u57fa\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u4e2d\uff0c\u4e09\u57fa\u78f7\u53ef\u4ee5\u4f5c\u4e3a\u8f85\u52a9\u914d\u4f53\uff0c\u63d0\u9ad8\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\u548c\u6d3b\u6027\u3002<\/p>\n

\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u4e09\u57fa\u78f7\u7684\u914d\u4f4d\u65b9\u5f0f\u5177\u6709\u9ad8\u5ea6\u53ef\u8c03\u6027\u3002\u901a\u8fc7\u6539\u53d8\u53cd\u5e94\u6761\u4ef6\u6216\u5f15\u5165\u5176\u4ed6\u914d\u4f53\uff0c\u5b83\u53ef\u4ee5\u5b9e\u73b0\u4ece\u5355\u9f7f\u5230\u591a\u9f7f\u914d\u4f4d\u7684\u8f6c\u6362\u3002\u8fd9\u79cd\u7075\u6d3b\u6027\u4f7f\u5f97\u4e09\u57fa\u78f7\u5728\u590d\u6742\u4f53\u7cfb\u4e2d\u4e5f\u80fd\u4fdd\u6301\u51fa\u8272\u7684\u8868\u73b0\uff0c\u5c31\u50cf\u4e00\u4f4d\u5584\u4e8e\u53d8\u901a\u7684\u5916\u4ea4\u5b98\uff0c\u603b\u80fd\u627e\u5230\u5408\u9002\u7684\u89e3\u51b3\u65b9\u6848\u3002<\/p>\n

\u72ec\u7279\u7684\u7535\u5b50\u6548\u5e94<\/h3>\n

\u4e09\u57fa\u78f7\u7684\u57fa\u7ed3\u6784\u8d4b\u4e88\u4e86\u5b83\u72ec\u7279\u7684\u7535\u5b50\u6548\u5e94\u3002\u8fd9\u79cd\u6548\u5e94\u4e0d\u4ec5\u5f71\u54cd\u7740\u5316\u5408\u7269\u672c\u8eab\u7684\u5316\u5b66\u6027\u8d28\uff0c\u4e5f\u4e3a\u53cd\u5e94\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u66f4\u591a\u53ef\u80fd\u6027\u3002\u4f8b\u5982\uff0c\u5728\u67d0\u4e9b\u52a0\u6210\u53cd\u5e94\u4e2d\uff0c\u4e09\u57fa\u78f7\u53ef\u4ee5\u901a\u8fc7\u5176\u4f9b\u7535\u5b50\u6548\u5e94\u589e\u5f3a\u53cd\u5e94\u6d3b\u6027\uff0c\u540c\u65f6\u6291\u5236\u526f\u53cd\u5e94\u7684\u53d1\u751f\u3002<\/p>\n

\u8fd9\u79cd\u7535\u5b50\u6548\u5e94\u7684\u5e94\u7528\u573a\u666f\u5341\u5206\u5e7f\u6cdb\u3002\u5728\u805a\u5408\u7269\u6539\u6027\u4e2d\uff0c\u4e09\u57fa\u78f7\u53ef\u4ee5\u8c03\u8282\u5355\u4f53\u7684\u805a\u5408\u901f\u7387\u548c\u94fe\u589e\u957f\u65b9\u5411\uff1b\u5728\u67d3\u6599\u5408\u6210\u4e2d\uff0c\u5b83\u5219\u80fd\u5f71\u54cd\u5206\u5b50\u7684\u5438\u6536\u6ce2\u957f\u548c\u8367\u5149\u5f3a\u5ea6\u3002\u6b63\u5982\u4e00\u4f4d\u7cbe\u901a\u7434\u827a\u7684\u6f14\u594f\u5bb6\uff0c\u4e09\u57fa\u78f7\u80fd\u591f\u7cbe\u786e\u63a7\u5236\u6bcf\u4e00\u4e2a\u97f3\u7b26\u7684\u5f3a\u5f31\u548c\u8282\u594f\uff0c\u8c31\u5199\u51fa\u7f8e\u5999\u7684\u5316\u5b66\u4e50\u7ae0\u3002<\/p>\n

\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027<\/h3>\n

\u4e0e\u5176\u4ed6\u6709\u673a\u78f7\u5316\u5408\u7269\u76f8\u6bd4\uff0c\u4e09\u57fa\u78f7\u5177\u6709\u51fa\u8272\u7684\u70ed\u7a33\u5b9a\u6027\u3002\u5373\u4f7f\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\uff0c\u5b83\u4f9d\u7136\u80fd\u591f\u4fdd\u6301\u7ed3\u6784\u5b8c\u6574\uff0c\u4e0d\u4f1a\u53d1\u751f\u5206\u89e3\u6216\u53d8\u8d28\u3002\u8fd9\u79cd\u7279\u6027\u4f7f\u5176\u5728\u9ad8\u6e29\u53cd\u5e94\u4f53\u7cfb\u4e2d\u8868\u73b0\u5c24\u4e3a\u7a81\u51fa\u3002<\/p>\n

\u5177\u4f53\u6765\u8bf4\uff0c\u4e09\u57fa\u78f7\u53ef\u4ee5\u5728\u9ad8\u8fbe200\u00b0C\u7684\u6e29\u5ea6\u4e0b\u7a33\u5b9a\u5b58\u5728\uff0c\u800c\u4e0d\u4f1a\u5f71\u54cd\u5176\u50ac\u5316\u6216\u914d\u4f4d\u6027\u80fd\u3002\u8fd9\u4e00\u4f18\u52bf\u5bf9\u4e8e\u67d0\u4e9b\u9700\u8981\u9ad8\u6e29\u64cd\u4f5c\u7684\u5de5\u4e1a\u8fc7\u7a0b\u81f3\u5173\u91cd\u8981\uff0c\u4f8b\u5982\u805a\u78b3\u9178\u916f\u7684\u5408\u6210\u548c\u73af\u6c27\u6811\u8102\u7684\u56fa\u5316\u3002\u5b83\u5c31\u50cf\u4e00\u4f4d\u8010\u5bd2\u6297\u6691\u7684\u52c7\u58eb\uff0c\u65e0\u8bba\u73af\u5883\u5982\u4f55\u6076\u52a3\uff0c\u90fd\u80fd\u575a\u5b88\u5c97\u4f4d\uff0c\u5b8c\u6210\u4f7f\u547d\u3002<\/p>\n

\u5de5\u4e1a\u5e94\u7528\u5b9e\u4f8b\uff1a\u4e09\u57fa\u78f7\u7684\u7cbe\u5f69\u821e\u53f0<\/h2>\n

\u5982\u679c\u8bf4\u4e09\u57fa\u78f7\u662f\u4e00\u4f4d\u624d\u534e\u6a2a\u6ea2\u7684\u827a\u672f\u5bb6\uff0c\u90a3\u4e48\u5de5\u4e1a\u5e94\u7528\u5c31\u662f\u5b83\u5c3d\u60c5\u5c55\u793a\u624d\u534e\u7684\u5e7f\u9614\u821e\u53f0\u3002\u8ba9\u6211\u4eec\u901a\u8fc7\u51e0\u4e2a\u5177\u4f53\u7684\u5de5\u4e1a\u6848\u4f8b\uff0c\u6df1\u5165\u63a2\u7a76\u4e09\u57fa\u78f7\u5982\u4f55\u5728\u5b9e\u9645\u751f\u4ea7\u4e2d\u5c55\u73b0\u5176\u72ec\u7279\u9b45\u529b\u3002<\/p>\n

\u5236\u836f\u5de5\u4e1a\u4e2d\u7684\u660e\u661f\u89d2\u8272<\/h3>\n

\u5728\u5236\u836f\u9886\u57df\uff0c\u4e09\u57fa\u78f7\u53ef\u8c13\u529f\u52cb\u5353\u8457\u3002\u4ee5\u6297\u764c\u836f\u7269\u7d2b\u6749\u9187\u7684\u5408\u6210\u4e3a\u4f8b\uff0c\u4e09\u57fa\u78f7\u5728\u5176\u4e2d\u626e\u6f14\u7740\u81f3\u5173\u91cd\u8981\u7684\u89d2\u8272\u3002\u5728\u5173\u952e\u7684\u9170\u5316\u6b65\u9aa4\u4e2d\uff0c\u4e09\u57fa\u78f7\u4e0e\u7898\u5316\u4e9a\u94dc\u5f62\u6210\u7684\u914d\u5408\u7269\u80fd\u591f\u6709\u6548\u5730\u4fc3\u8fdb\u53cd\u5e94\u8fdb\u884c\uff0c\u663e\u8457\u63d0\u9ad8\u4e86\u4ea7\u7387\u548c\u7eaf\u5ea6\u3002<\/p>\n

\u7279\u522b\u662f\u5728\u624b\u6027\u836f\u7269\u7684\u5408\u6210\u4e2d\uff0c\u4e09\u57fa\u78f7\u7684\u4f18\u52bf\u66f4\u52a0\u51f8\u663e\u3002\u901a\u8fc7\u4e0e\u624b\u6027\u914d\u4f53\u534f\u540c\u4f5c\u7528\uff0c\u5b83\u53ef\u4ee5\u5b9e\u73b0\u9ad8\u7acb\u4f53\u9009\u62e9\u6027\u7684\u8f6c\u5316\u3002\u4f8b\u5982\uff0c\u5728\u03b2-\u5185\u9170\u80fa\u7c7b\u6297\u751f\u7d20\u7684\u5408\u6210\u4e2d\uff0c\u4e09\u57fa\u78f7\u8f85\u52a9\u7684\u4e0d\u5bf9\u79f0\u6c22\u5316\u53cd\u5e94\u53ef\u4ee5\u8fbe\u523095%\u4ee5\u4e0a\u7684ee\u503c\uff08\u5bf9\u6620\u4f53\u8fc7\u91cf\uff09\u3002<\/p>\n\n\n\n\n\n\n\n
\u836f\u7269\u540d\u79f0<\/th>\n\u5408\u6210\u6b65\u9aa4<\/th>\n\u4ea7\u7387\u63d0\u5347\u5e45\u5ea6<\/th>\n<\/tr>\n<\/thead>\n
\u7d2b\u6749\u9187<\/td>\n\u9170\u5316\u53cd\u5e94<\/td>\n+25%<\/td>\n<\/tr>\n
\u03b2-\u5185\u9170\u80fa<\/td>\n\u4e0d\u5bf9\u79f0\u6c22\u5316<\/td>\n+30%<\/td>\n<\/tr>\n
\u5421\u5576\u916e\u7c7b<\/td>\n\u5076\u8054\u53cd\u5e94<\/td>\n+20%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u9ad8\u5206\u5b50\u6750\u6599\u9886\u57df\u7684\u521b\u65b0\u5148\u950b<\/h3>\n

\u5728\u9ad8\u5206\u5b50\u6750\u6599\u9886\u57df\uff0c\u4e09\u57fa\u78f7\u540c\u6837\u5c55\u73b0\u4e86\u975e\u51e1\u7684\u521b\u9020\u529b\u3002\u4ee5\u805a\u78b3\u9178\u916f\u7684\u5408\u6210\u4e3a\u4f8b\uff0c\u4f20\u7edf\u65b9\u6cd5\u9700\u8981\u4f7f\u7528\u5267\u6bd2\u7684\u5149\u6c14\u4f5c\u4e3a\u539f\u6599\uff0c\u800c\u91c7\u7528\u4e09\u57fa\u78f7\u50ac\u5316\u7684\u754c\u9762\u6cd5\uff0c\u5219\u53ef\u4ee5\u7528\u66f4\u4e3a\u5b89\u5168\u7684\u4e8c\u6c27\u5316\u78b3\u66ff\u4ee3\u5149\u6c14\uff0c\u5b9e\u73b0\u4e86\u7eff\u8272\u73af\u4fdd\u7684\u751f\u4ea7\u5de5\u827a\u3002<\/p>\n

\u6b64\u5916\uff0c\u5728\u9ad8\u6027\u80fd\u5de5\u7a0b\u5851\u6599\u7684\u5236\u5907\u4e2d\uff0c\u4e09\u57fa\u78f7\u8fd8\u53ef\u4ee5\u7528\u4f5c\u94fe\u8f6c\u79fb\u5242\uff0c\u7cbe\u786e\u63a7\u5236\u805a\u5408\u7269\u7684\u5206\u5b50\u91cf\u548c\u5206\u5e03\u3002\u8fd9\u79cd\u8c03\u63a7\u80fd\u529b\u5bf9\u4e8e\u751f\u4ea7\u5177\u6709\u7279\u5b9a\u673a\u68b0\u6027\u80fd\u7684\u6750\u6599\u5c24\u4e3a\u91cd\u8981\u3002\u4f8b\u5982\uff0c\u5728\u6db2\u6676\u805a\u5408\u7269\u7684\u5408\u6210\u4e2d\uff0c\u901a\u8fc7\u8c03\u8282\u4e09\u57fa\u78f7\u7684\u7528\u91cf\uff0c\u53ef\u4ee5\u5f97\u5230\u4e0d\u540c\u7c98\u5ea6\u548c\u6d41\u52a8\u6027\u7684\u4ea7\u54c1\uff0c\u6ee1\u8db3\u591a\u6837\u5316\u7684\u9700\u6c42\u3002<\/p>\n

\u7cbe\u7ec6\u5316\u5de5\u4e2d\u7684\u5168\u80fd\u9009\u624b<\/h3>\n

\u5728\u7cbe\u7ec6\u5316\u5de5\u9886\u57df\uff0c\u4e09\u57fa\u78f7\u7684\u5e94\u7528\u66f4\u662f\u65e0\u6240\u4e0d\u5728\u3002\u5728\u67d3\u6599\u5408\u6210\u4e2d\uff0c\u5b83\u53ef\u4ee5\u7528\u4f5c\u52a9\u50ac\u5316\u5242\uff0c\u63d0\u9ad8\u53cd\u5e94\u7684\u9009\u62e9\u6027\u548c\u6548\u7387\u3002\u4ee5\u5206\u6563\u67d3\u6599\u7684\u751f\u4ea7\u4e3a\u4f8b\uff0c\u91c7\u7528\u4e09\u57fa\u78f7\u50ac\u5316\u7684Suzuki\u5076\u8054\u53cd\u5e94\uff0c\u53ef\u4ee5\u5c06\u4ea7\u7387\u63d0\u9ad8\u81f390%\u4ee5\u4e0a\uff0c\u540c\u65f6\u51cf\u5c11\u526f\u4ea7\u7269\u7684\u751f\u6210\u3002<\/p>\n

\u5728\u9999\u6599\u548c\u9999\u6c34\u7684\u5408\u6210\u4e2d\uff0c\u4e09\u57fa\u78f7\u540c\u6837\u53d1\u6325\u4e86\u91cd\u8981\u4f5c\u7528\u3002\u901a\u8fc7\u4e0e\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u534f\u540c\u4f5c\u7528\uff0c\u5b83\u53ef\u4ee5\u5b9e\u73b0\u590d\u6742\u5206\u5b50\u9aa8\u67b6\u7684\u6784\u5efa\uff0c\u4e3a\u65b0\u578b\u9999\u6599\u7684\u5f00\u53d1\u63d0\u4f9b\u4e86\u6709\u529b\u5de5\u5177\u3002\u4f8b\u5982\uff0c\u5728\u5408\u6210\u5e7f\u85ff\u9999\u916e\u7c7b\u4f3c\u7269\u65f6\uff0c\u4e09\u57fa\u78f7\u8f85\u52a9\u7684\u7fb0\u57fa\u5316\u53cd\u5e94\u663e\u8457\u63d0\u5347\u4e86\u53cd\u5e94\u6548\u7387\u548c\u4ea7\u54c1\u8d28\u91cf\u3002<\/p>\n

\u6280\u672f\u6311\u6218\u4e0e\u89e3\u51b3\u65b9\u6848\uff1a\u4e09\u57fa\u78f7\u7684\u6539\u8fdb\u4e4b\u8def<\/h2>\n

\u5c3d\u7ba1\u4e09\u57fa\u78f7\u5728\u591a\u4e2a\u9886\u57df\u5c55\u73b0\u4e86\u5353\u8d8a\u6027\u80fd\uff0c\u4f46\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u4ecd\u9762\u4e34\u4e00\u4e9b\u6280\u672f\u6311\u6218\u3002\u8fd9\u4e9b\u95ee\u9898\u5982\u540c\u6500\u767b\u9ad8\u5cf0\u9014\u4e2d\u9047\u5230\u7684\u9661\u5ced\u5ca9\u58c1\uff0c\u867d\u7136\u589e\u52a0\u4e86\u524d\u884c\u7684\u96be\u5ea6\uff0c\u4f46\u4e5f\u6fc0\u53d1\u4e86\u79d1\u7814\u4eba\u5458\u4e0d\u65ad\u63a2\u7d22\u7684\u70ed\u60c5\u3002<\/p>\n

\u7a33\u5b9a\u6027\u95ee\u9898\u53ca\u5176\u5e94\u5bf9\u7b56\u7565<\/h3>\n

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\u53c2\u8003\u6587\u732e<\/h2>\n

[1] March, Jerry. Advanced Organic Chemistry: Reactions, Mechanisms, and Structure. John Wiley & Sons, 2007.<\/p>\n

[2] Solomons, T.W. Graham, and Craig B. Fryhle. Organic Chemistry. John Wiley & Sons, 2014.<\/p>\n

[3] Carey, Francis A., and Robert M. Giuliano. Organic Chemistry. McGraw-Hill Education, 2016.<\/p>\n

[4] Smith, Michael B., and Jerry March. March’s Advanced Organic Chemistry: Reactions, Mechanisms, and Structure. John Wiley & Sons, 2007.<\/p>\n

[5] Sandler, Stanley R. Organic Functional Group Preparations. Academic Press, 2014.<\/p>\n

[6] Larock, Richard C. Comprehensive Organic Transformations: A Guide to Functional Group Preparations. John Wiley & Sons, 2010.<\/p>\n

\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/-25-S-Lupragen-N202-TEDA-L25B.pdf<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/43944<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/44807<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/957<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/40526<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/40439<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.cyclohexylamine.net\/tertiary-amine-catalyst-dabco-pt303-catalyst-dabco-pt303\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/Dibutyltin-monobutyl-maleate-CAS-66010-36-4-BT-53C.pdf<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/2-dimethylamineethanol\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/FASCAT4201-catalyst-CAS-818-08-6-dibutyl-tin-oxide.pdf<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":"

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